You should know
...about Voltage: You can set there what You want, because it has no effect and does not change real voltage of PSU. If You watched cgminer script in S4 unit You knew, that there is always set the same value 0725.
...about S4 PSU: it is 80 GOLD PLUS PSU, running at the very top of its abilities. If You overburn it (by changing voltage via ssh in cgminer script), You can damage it, and I would like to see You how are You replacing it.
...about GHs hashing power: overclocking is lowering efficiency rappidly, if You get 10% more GHs, You loose more then 10% of energy at the same time. No more words about hw errors growing volume. I do not see any sense doing that, but if You want to play, play.