You create 5 different pools with different priorities, but they'll need to be the 5 highest priorities in your list. I have mine setup as 4,5,6,7,8,9 (lets me add something as 1,2,3 if I wanted to). Miningpoolhub will automatically shut down the ports it's not using when it switches between them. For example, if it's auto-switching on x11, the x13, x15, quark and qubit pools will show as 'down' in the baikal because miningpoolhub has shut them off, letting the baikal auto switch to them.
Do you own a Baikal?