At that time, the whole world is now dependent to internet and surely the international organizations would never let the internet to freeze at any point (unless all antennas, satellites and servers are all destroyed at the same time). Even today that bitcoin is not the main payment method, the international organizations will, also, not let this type of event happens. Not just the payments and transactions are affected but also businesses will be harmed.
As for the alternative if bitcoin freezes,
Use cash.