Thanks salty. I know I can settle any debt with the minimum of £1 up to any value but it is only a small debt and I want to just wind the guy up. Could you read my OP and see what you think?

Yes if they don't accept your remittance offered in £1 coins + the rest of the change allowed, and subsequently take you to small claims court to get the money off you, the court would be satisfied that you had offered to settle the debt using legal tender and that they had refused it. If you try to give them 1p, 2p, 5p etc. coins only, you'll get a rollocking.
http://www.guardian.co.uk/money/shortcuts/2012/may/15/what-can-you-buy-just-with-1p-and-2pI think you are misunderstanding my question.
Say I want to settle a debt of 0.22p.....
Am I able to pay with 20 x 1p coins and 1 x 2p coin legally?