I tried running from command line and it shows no errors. The window closes and windows says it errored and closed.
Is there any other way to capture any data as to what is happening?
Hardware is a 7970, 5970, 5830. AMD processor, 8gb RAM, Raid 1 on the drives.
IIRC there are some issues with mixing 7xxx and 5xxx GPUs, like Luke-Jr said, most likely drivers. As a test, pull out the 7970 and see if you can get it stable with just the 5xxx GPUs.