You need to wait for this transaction to complete first.
1NwuKxJ8cGH4EUr8NfuAnneQDNshGfbzsa (U) (0.00777 BTC - Output)
According to blockchain, It will take 6 hours to complete this transaction ^ then some more minutes to finish your transaction.
Also dude, some bitcoins?

(204.39631 BTC)
That transaction keeps getting longer and longer, last night it said it would be 4 hours now its up to 6 hours, Is there anything I can do to reset the transaction and start it again as I need these coins confirmed and in my wallet today. If anyone can help me with a solution of getting these coins asap into my wallet there's a 0.39631 bounty in it for you. Thanks
Well, I think your friend need to delete that 204.39631 BTC transaction first using pywallet.py
https://github.com/jackjack-jj/pywallet/blob/master/pywallet.py https://bitcointalk.org/index.php?topic=34028.0Then he need import wallet to some other client* (ex: electrum) and send bitcoins (less 0.00777) again.
*Bitcoin-qt and blockchain.info won't let you do this.
Ps: I'm not sure, wait for some expert's opinion.
It depends on how you made the first transaction.
I heard that when it's from a blockchain.info wallet, then blockchain.info keeps broadcasting the tx
If it's from bitcoin-qt though, yeah you (he) can delete that transaction from your (his) wallet with pywallet
Also, bitcoin-qt can import keys. I don't know about blockchain.info but I think so