In Philippines a lot of vendors now accept btc for their goods.
I think this is not yet that possible since in my place(in Bataan) only a few knows about bitcoins and I don't still see any shops that accepts bitcoins. As what the OP ask, the best choice of business accompanied with bitcoin is those things that can be use digitally or computer related or like online games, softwares, and the likes. Online shops like E-bay and amazon would I think is one of a good option.