It is possible to make direct withdrawal request without e-mail access/confirmation?
No. In times I used polo as I remember whenever I made the withdrawal request I received the confirmation email and without the email I did not withdraw anything, so if you gave your account to someone to make a trade for you (which I do not recommend people do), this person would not make withdrawals.
Remember: do not trust anyone, you never know when a good person becomes a bad person and when an honest person becomes a thief and a liar