Man I said I wouldn't comment on this as it has a little of the 'Workers of the World Unite' type of fluff but I like your enthusiasm.
So you mentioned the usage of the Internet and later focused to the web. There are so many other actors and roles using the network itself over TCP using differing protocols to exchange all types of data to aid in commerce, GIS, medicine, etc. So I don't really see where you are going with this because the premise seems thin.
Regarding this post you are basically describing the market place where two or more individuals enter into a mutually beneficial exchange. Adam Smith's Invisible Hand if you will. Regarding changing the system which is a statist/collectivist system which favors centralization and politically connected players the question is perhaps as old as time. It is a questions of the struggle between those that would control others and those that favor freedom and liberty.
From a practical standpoint changing the balance between centralized control systems and individual liberty can be done in many ways, toward one end of the spectrum and back again. One way is of course changing who controls the currency and here we are.
Focusing on the practical uptake of BTC or a P2P economy is perhaps where the loin's share of intellectual capital should be spent because philosophically most people here will agree with your underlying premise of which I believe is how to change/influence how currency systems currently operate (I could have misunderstood your main thrust though and I apologize if that's the case).
At the end of the day there are two ways that are commonly used to solve the challenges of the allocation of scare resources. They are either economic or they are political in nature. One requires choice and the other requires force.