en.bitcoin.it/wiki/Transaction_fees#SendingCurrently, any transaction sending less than
BTC0.01 absolutely requires a transaction fee of at least
BTC0.0001. Assuming you want to transfer
BTC0.00001 to your friend, not only will
you have to pay this fee, but
your friend will also have to pay an additional
BTC0.0001 to send his coins anywhere else. Since the required fee is more than he has, he will not be able to spend his coins at all, and the whole situation is entirely your fault.
Bitcoin is not suitable for microtransactions, and anyone who told you differently is a liar.