Armory "Root Keys" are proprietary
I don't think the method is actually 'proprietary'. That would mean that nobody else was allowed to use their method.
and, as far as I am aware, only work with Armory...
Right, but that is only because nobody uses the Armory method. They could if they wanted.
Instead they use the standard (BIP-32) hierarchical key generation method.
Armory would probably have used BIP-32 as well, but was developed before BIP-32 was created.