but there are many known attacks which can be used against Tor, plus possible 0-days against the browser, so you can never feel 100% anonymous.
Qubes OS + Whonix is a pretty good alternative compared to just using the Tor browser on Windows.
Also, even if you treat Tor as perfect, it's really difficult to remain consistently anonymous; for example, you might via Tor use the same email address to order something shipped to you as you use to speak out against your oppressive government, and that's a link that can be exploited. Even though Tor is pretty flawed, being far behind state-of-the-art research, it's these non-Tor anonymity failures which almost always get people. This was the case for Ross Ulbricht, for example. As I always say: if you think that you're perfectly anonymous, then you're wrong. Think of even the best anonymity tech as a light bulletproof vest which will increase your survivability a bit, not as an impenetrable wall.
Ross Ulbricht made some pretty bad mistakes, if anything it's more of a surprise why he wasn't caught sooner. But some have been caught by things as seemingly innocuous (to an average person) as their writing style that could be connected to their real identity.