I doubt Bet365 can send more than your initial deposit to your card (100 EUR), usually these payouts are just a refund of the initial payment. I guess the remaining should be withdrawn by bank transfer.
Anyway just email them and tell them you want to withdraw all by bank transfer, usually they should let you do it.
No, they won't, I've been through this when I deposited a few $ via aa card and while playing and losing for a year (I only place small 1-3euro bets for fun) my card expired and when I registered a new card they've told me that they won't deposit the winning to the new ones unless deposits from the new card exceed the ones from the older one. Yeah...morons!
And I did receive more than 100euros from them via card deposits and it was no problem and if I remember correctly they did it in less than 48 hours.
F* AML regulation, I'm not going to risk my card and my betting account for this, I'll just wait slowly till I lose all the earning through the year...

Back to wirex...
I got a notification about a 5 AUD donation on my behalf from wirex for the bushfires in Australia, and it said: "open the app to find out how"...I opened the app, I closed the app I opened and pushed and tapped and...you get the idea...anyone knowing how this works?
Sorry to hear, but by the way if your card was expired, but the new card was issued by the same bank (attached to the same bank account) then no big deal, the funds will still reach the bank account even though the card has expired. I am pretty confident about this but you can ask the question to your bank (or even Bet365 surely they should be aware of it).
Sorry again for the off topic.