Kane has already rejected a move to PSG despite their making a way bigger offer than Bayern Munich. He wanted to sign for Bayern Munich instead. But no matter how much the player wants this deal it is still up to Tottenham chairman Levy's last words about the deal. PSG offered 100 million euros according to rumours.
Therefore I don't expect him to accept an offer lower than that level from Bayern Munich as well. Levy is aware that they are going to lose him for free if he doesn't let him go now. He had better not let this happen if he doesn't want to lose him like that.
I don't remember the offer from PSG and how much they wanted to pay him I'm sure PSG could pay him more than Baytern MUnich because of their better financial situation they have, but still, I think Kane will join Bayern Munich because he knows he can reach his goals there and unlike Tottenham, Bayern Munich got a much better situation in the champions league.
I think Paris SG could be chosen instead of Bayern Munich. Paris SG has a staff as qualified as Bayern Munich. Although the possibility of Mbappe's transfer is confusing, Harry Kane can be successful there as well. Of course, we know that both teams want him. Now he will shape his career according to his choice.