Can't say PSG got more chances this season just because they have Enrique in their team because we all know they lost many superstar players and PSG can't find players like Messi anymore, PSG is even close to losing Mbappe too. I think there is not much chance for PSG to achieve anything in the next champions league.
To do well in the Champions League, PSG will have to reorganize the team again. It is not possible to do well in such a big tournament like the Champions League with the current team. If PSG gives Luis Enrique the freedom to buy as many players as he wants, Luis Enrique can rebuild this team. If Luis Enrique is given the freedom to buy as many players as he wants, he will start from the defense to fine tune the team. First defense, then midfield, then forward, if the team is arranged in this way, then this team can be expected in the Champions League, otherwise it is not possible to do well in the next season with the current team.