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Imagine Kane to miss a penalty or one-on-one position in that Mainz game. He should feel the pressure more, Bayern is very different than Tottenham.
The good thing here is that Kane actually acknowledges the pressure from the Bayern fans or media and he thinks that may even sharpen his mentality. It seems he felt dull playing for Tottenham maybe because the team's management didn't have enough drive or ambition to win trophies.
Tottenham were a mediocre team. Their aim was to keep the performance somewhat stable and stay in the top 5/6 of the points table . They never had such lofty ambitions as winning the title. On the other hand bayern munich's scenario is completely different. This team dominates the bundesliga. The bundesliga title is won every season. At the same time their goal is to win the Champions league title . A completely different environment for harry kane. If harry kane enjoys this he will be more confident and able to perform better. Bayern Munich have the potential to dominate the Champions League and Bundesliga if Harry kane continues his form.