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Arsenal just destroyed PSV in this match and i was thinking that PSV was gonna make a lot of troubles but they got destroyed. I think in Netherlands it will be a different match and that PSV might take some points there. Still Arsenal started the champions league really good
PSV can take some points against Sevilla or Lens, but I'm sure they won't manage to take any points against Arsenal. PSV can take advantage of the home game to play better against their visitors, they should be favored.
The second match in the group stage will take place in early October, Sevilla is the opponent. PSV, playing at home, will certainly take advantage of home advantage to win, but if Sevilla is able to put up a good fight then both teams will have difficulty winning the match. The possibility is may with PSV, but no one knows for sure what will happen.