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This was the best decision of Harry Kane's career. And I would say Kane should have left Tottenham earlier. Tottenham management had no desire to win the title. They did not form a strong squad to compete for the title. Harry Kane has chosen the Bayern Munich team. Munich has ambitions to win the Champions League title. They won the Bundesliga title every season while also trying their best to win the Champions League title. If Harry Kane can maintain this consistency of performance then Bayern Munich have chances to win Champions League title this season.
Kane cannot do it alone without support and good performance from his teammates. Bayern Munich is so far the favorite in the Champions League after Manchester City, they are even above Real Madrid in terms of probability this season to win the Champions League title.
However, there are many people who doubt Manchester City's ability to defend their title this season. They have not made history like that throughout their participation in the Champions League, but that does not mean it is impossible when the depth of the squad and the tactical ability of the coach are better than their opponents.