I'm not much positive about Barcelona's chance to eliminate Napoli honestly. Because their game is just not good enough. I believe that they haven't faced a real challenge yet. Porto were the second strongest team in the group but Barcelona won against them twice anyway. But I think Napoli are a bigger challenge than Porto for them.

Napoli have a stronger squad in the first place. They have a very dangerous player like Osimhen in their offense line. They are just trying to improve their form lately. But until this matchup I think Napoli will be in a better shape than now. If Barcelona don't make improvement at the same time then they can really say goodbye to the CL early.