* Parma - AC Milan => AC Milan
* Inter Milan - Lecce => Inter Milan
* Fiorentina - Venezia => Fiorentina
* AS Roma - Empoli => AS Roma
* Napoli - Bologna => Napoli
* Hellas Verona - Juventus => Juventus
Big clubs don't have to meet strong opponents in this match day except Napoli will face with Bologna. Bologna is no longer a strong version like past season after losing some important people from coach to players. They are weaker in human resource quality but they will be able to challenge Napoli that seems to be in trouble and might face with a crisis in this season.
I agree with most of your choices that big clubs will win and have three points but I beg on differ with Napoli vs Bologna match. Napoli will not have three points from Bologna but it would be too much for Bologna to beat Napoli too.