Juventus vs PSV which will take place in the house of Juventus. But my prediction is a little bad for Juventus.
I mean not actually doubting Juventus performance at this time, but the problem in the domestic match, Motta care team experienced a slight decline like last season. When fighting Rome and Empoli which should be a team that is not so difficult, the fact that Juventus can only get a draw.
While PSV has better achievements in the previous several matches look more consistent. And my prediction is that the results of this first match are likely to end in a draw.
What about your predictions?

In my opinion PSV will win this game, they are a team that has been performing well in the last 4 years and even in European competitions they are also improving, last season they managed to draw against Arsenal and Dortmund and beat Sevilla in European Champions League games. And as you said, Juventus continue to be an inconsistent team, and their biggest strength is in defense, but PSV's biggest strength is in attack with
5 games they have scored 20 goals and they are also strong in defense. I see some football analysis pages saying that Juventus will win. The bookmakers are also placing Juventus as favorites, but I think PSV is better prepared to win the game.
Looking at both teams Juventus and PSV is a bit difficult, PSV does have a good record and in their domestic league they are quite dominant which we can conclude that they are the strongest and most consistent team in the Dutch league so far, while if thrown at Juventus which in the last few seasons has been very chaotic with internal problems and the team has made this team uncontrollable and its performance has fluctuated, that's what makes us doubtful about Juventus, but when compared between the Eredevisie leagues, of course Juventus' experience is more and more impressive with its Serie A.
But sometimes we have to fight the bookies to try our luck in matches like this.