It is hard to predict who will win between Juventus and PSV. PSV is doing very well in their league, winning a lot of games. Juventus on the other hand they have some problems inside team making their games unpredictable. But Juventus has played in strong league Serie A for long time which helps them. Still PSV is playing well and Juventus is unpredictable so anything can happen. Sometimes it is good to take chance and bet against the team that is expected to win because surprises can happen in football.
PSV Eindhoven is currently occupying the first position in the Eredivisie. They have not lost any game and have gathered fifteen points from five games. Juventus are not also doing badly in the Italian Seria A. They are in third position with eight points. They have not conceded any goal, which shows that they have a good defence. However, we cannot compare the Dutch League with the Seria A, the latter is more difficult. Juventus are favourites in this game, but PSV is also a good side. I wouldn't place my bet on PSV because Juventus has a greater chance of winning, and playing at home in Allianz Stadium is also an advantage.
Both teams actually have a good performance in their respective leagues at the moment, Juventus and PSV are quite consistent playing in the domestic league although indeed Juventus' journey in Serie A is not as perfect as PSV who continues to win in the Eredivisie, but we cannot judge the two teams today only based on their achievements in the league considering the comparison of quality and also competition in Serie A and also the Eredivisie which is very different at the moment, so indeed the level of performance of the two teams in playing in the Champions League will also be very different later, so far PSV is a team that is quite consistent in playing in European competitions but Juventus who has won the Champions League 2 times of course have a better mentality when playing in the Champions League, last season Juventus failed to play in the Champions League and I think this season they have certainly prepared the team as best as possible to be able to compete in the championship, ths season is Motta first season in charge of Juventus so I think he will take advantage of every game available to win, my prediction is that Juventus will win with a score of 3-1 over PSV in the first match of the Champions League this season.