Liverpool 2.07 vs 3.67 Real Madrid.
My choice is Liverpool. They got advantage to play at home. But, I respect Real Madrid as their opponent. The last time they lost against Madrid at Anfield, and it's time to revenge.
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I'm not sure if playing at home is actually such a big advantage for Liverpool. Looking at their league game statistics, the average points per game for them is slightly higher for away games than for the home ones (a difference of 0.1 point). That's largely due to their home loss to Nottm Forest back in September.
It's not a good game to bet on, in my opinion, as it's one of those where anything is possible, from a goalless draw to a high win for either team. It should be a good one to watch though.