Compra bitcoins online en Ecuador, transferencia bancario / Buy bitcoins online using Ecuadorian bank transfer:
https://localbitcoins.com/ad/89640/purchase-bitcoin-bank-transfer-ecuador-ecuador

Compra bitccoins en effectivo USD en Loja/Vilcabamba / Buy bitcoins with cash in Loja/Vilcabamba:
https://localbitcoins.com/ad/89645/buy-bitcoins-with-cash-loja-ecuador

Probably the best way to get your hands on bitcoins in Ecuador right now. Website is coming up at http://bitcoinsecuador.com very soon.
Other options for buying include Western Union and Moneygram. 100% feedback on localbitcoins.