Liverpool have already qualified for the last 16. Their only motivation in this game is probably to maintain their position at the top of the standings because Barcelona can still overtake them. On the other hand, PSV are still fighting to qualify, the result in this match will be very crucial, they must rely on this game to secure their position.
The statistics of both also place Liverpool as the favorite team, Liverpool managed to win in their last 5 matches against PSV in all competitions, PSV also recorded an interesting record, they are unbeaten in the Home match this season in all competitions.
If we assume that Liverpool will not be defeated in Holland, I think Barcelona's chances of overtaking them are a bit low. Of course, if Barcelona wins in terms of points and Liverpool loses, the leadership will change hands, but I think they will beat PSV in Holland. Although the Dutch representative is a strong team, I don't think they will play an effective game against Liverpool. Because Liverpool is one of the best teams in the world this year. They will probably win the Champions League.
We probably going to see some unexpected results tonight in the champions league, at this stage of the league it's not about those teams at the top but below because the results of today's game will determine their fate in the league. And like the last kicks of a dieing horse PSV Eindhoven would be giving it their all in this game against a Liverpool side that has nothing at stake no matter which way the results go.
I think PSV has a higher chances of winning this game plus the home advantage it puts them on a better position to impress their home fans and maintain their home unbeaten run in all games this season.