About the match between Juventus vs PSV, it looks like PSV will be able to beat Juventus, or it looks like PSV will succeed in becoming the team that advances to the next round. Maybe, in the first leg later because will be played at Juventus, the result could be a draw, because so far this season I still see Juventus as weak in attack so they don't have good aggressiveness. With this factor, it is possible that PSV will beat Juventus in the second leg, because in the second leg PSV will also play at home. But yes, I also realize that Juventus are an elite team, but in my view Juventus are not too good to be able to advance further in the Champion League this season.
Both teams is experience team in this competition this because they almost regularly to participate for every season but indeed in the term of achivement PSV is below to Juventus because in the last 20 years PSV highest achievement is semifinal on season 2004/2005 and since that year PSV similar liked a mediocre team who always be failed at group stages
Juventus match results is hard to predicted this because they unable to playing consistent even against weak teams Juventus is very often failed to win and last match of Group phase is very dissapointing for Juventus because they were lost from Benfica
For the first leg this match will be helded at Juventus home ground and i am sure they will be attempts to beat PSV because if Juventus won second leg would be more easy for them and recently both teams has been met on group phase with Juventus as the winner and i think Juventus will be able to repeat that result again or beat PSV