About the match between Juventus vs PSV, it looks like PSV will be able to beat Juventus, or it looks like PSV will succeed in becoming the team that advances to the next round. Maybe, in the first leg later because will be played at Juventus, the result could be a draw, because so far this season I still see Juventus as weak in attack so they don't have good aggressiveness. With this factor, it is possible that PSV will beat Juventus in the second leg, because in the second leg PSV will also play at home. But yes, I also realize that Juventus are an elite team, but in my view Juventus are not too good to be able to advance further in the Champion League this season.
I don't think PSV will be able to win Juventus. Even though Juventus form this season has been not been so good, they have dropped points in matches that they should have won, I think their overall squad depth and experience in European competitions give them an edge over PSV. I doubt PSV have the technical ability or experience needed to eliminate Juventus.