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That is smart look at Napoli upcoming match against AC Milan because Napoli is strong club with powerful attack but their recent games show clear weakness in defense proving they are not solid enough at back after letting in two goals against Pisa. This defensive problem makes game against strong rival like Milan very risky as Milan can easily use open spaces left by Napoli constant attack which is why betting on Both Teams to Score is good idea since it uses facts that Napoli scores lot but also lets in goals easily.
Yes, I agree with your assumption. It's true that if we bet on one of these teams, the risk is much greater. Because we know not which team will win this match. Currently, the performance of both teams seems quite balanced, making it difficult to predict which team will win. Therefore, placing a BTTS bet in this match might be much better, as we know there will definitely be goals in this match. I think both teams have equally strong attacking lines.
Therefore, it's highly unlikely that this match will end goalless. But if you're willing to take a big risk, I think you can bet on Milan in this match. Milan will benefit from the venue. This match will be held at Milan's home ground, so Milan will certainly be favored in this match, considering the venue. But obviously, choosing that is extremely risky, as Napoli certainly doesn't want to lose its winning record, wherever they play or against whomever they play. So, I think a BTTS is a very good move in this match.