Cash, in hand, from person A to person B.
Other than that, I recommend Bitcoin

.
You could just buy some Bitcoin and have it sent straight to his address, then the other person can just sell it for some fiat money, same day.

Right, I was thinking BTC -> FIAT.

I was just wondering online what is the best way to push FIAT to another FIAT account. Thanks for the reply.

Your answer lies in the web address: BitCointalk

Hahaha.....I know , I know ...I suppose I should have posted this in off-topics ...