Think about the economics:
Once you fill up 100 masternodes, there is no longer any buyer who can make a masternode. Therefore, no buyer will purchase the coin to make more MNs, so they will need another reason to purchase. What other reason is there? Without another reason, as soon as you hit 100 MN, demand might collapse and take your price down with it.
I think it is a good idea to try, but there needs to be a reason to "demand" EMC. The demand from making MNs will go away at 100 MNs, so you must create another source of demand.