Liverpool 2.07 vs 3.67 Real Madrid.
My choice is Liverpool. They got advantage to play at home. But, I respect Real Madrid as their opponent. The last time they lost against Madrid at Anfield, and it's time to revenge.
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I'm not sure if playing at home is actually such a big advantage for Liverpool. Looking at their league game statistics, the average points per game for them is slightly higher for away games than for the home ones (a difference of 0.1 point). That's largely due to their home loss to Nottm Forest back in September.
It's not a good game to bet on, in my opinion, as it's one of those where anything is possible, from a goalless draw to a high win for either team. It should be a good one to watch though.
If it was the Real Madrid we know about, no one everly dares to bet against them in any condition. But the Real Madrid of today, I am not so confident that they will be able to win Slot boys. However it does not mean that they will outrightly lose. If I will advise anyone to bet on the game, they should just wait till few days or hours to the match. Many players could be injured in this international break and they will be unavailable for that great match. Let's not rush into it.
For some teams, international break make them, for some, it mares them.