Yes, of course PSV has great motivation when they were able to beat Liverpool and with that they also have the ambition to continue racing in the Champions League. Juventus must certainly be aware of PSV's collective style of play because if they are careless, they will party again. Motta's presence at Juventus did not have a significant impact so it is difficult to guarantee that they will be able to talk a lot in the elite European competition. But the draw that brought these two teams together is of course very balanced.
Juventus must be able to win at home when hosting PSV even though the PSV team has better motivation when they were able to beat a strong team like Liverpool in the Champions League this season in the previous standings. However, for the match in the play-off round, I think both teams must play better because PSV also should not underestimate the Juventus team even though the team is not very consistent if we look at its current domestic league. Because in the Champions League, each team has a very different motivation when facing any opponent.