Yes, of course PSV has great motivation when they were able to beat Liverpool and with that they also have the ambition to continue racing in the Champions League. Juventus must certainly be aware of PSV's collective style of play because if they are careless, they will party again. Motta's presence at Juventus did not have a significant impact so it is difficult to guarantee that they will be able to talk a lot in the elite European competition. But the draw that brought these two teams together is of course very balanced.
Juventus must be able to win at home when hosting PSV even though the PSV team has better motivation when they were able to beat a strong team like Liverpool in the Champions League this season in the previous standings. However, for the match in the play-off round, I think both teams must play better because PSV also should not underestimate the Juventus team even though the team is not very consistent if we look at its current domestic league. Because in the Champions League, each team has a very different motivation when facing any opponent.
When PSV beat Liverpool we have to see the conditions at that time Liverpool were already safe at the top of the standings so of course Liverpool did not show maximum performance. I also do not underestimate PSV because they performed well in the group stage this season. Even PSV Eindhoven is ranked 14th in the standings with 14 points, and is two points ahead of Juventus who is in 20th position. Likewise if we look at the domestic league, both teams perform differently, PSV is better than Juventus.
However, it must also be seen that Juventus in the previous match when they were still in the group stage in the first match Juventus managed to beat PSV, and in this playoff match will be their second meeting of course Juventus has good capital from PSV especially this match. Moreover, this match is played at Juventus' home ground, this will be an extra strength for Juventus to steal three points. Even so, this match will be tight, considering that both teams have great ambitions to be able to qualify for the last 16 of the UCL League but once again I think Juventus' chances are greater than PSV.